FIELD: chemistry.
SUBSTANCE: method involves dichlorinating glycerol with gaseous hydrogen chloride at temperature of 70-140°C in the presence of a carboxylic acid and a water-insoluble organic solvent, wherein the process is carried out in a combined reaction/rectification reactor, and the organic solvent is selected such that it forms an azeotrope with water but not with glycerol dichlorohydrins.
EFFECT: method reduces contact time and increases output of glycerol dichlorohydrins.
3 cl, 1 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING DICHLOROPROPANOLS FROM GLYCERINE | 2004 |
|
RU2356878C2 |
EPICHLOROHYDRIN PRODUCING METHOD | 2016 |
|
RU2628801C1 |
PROCESS FOR PREPARING GLYCERIN DICH OROHYDRINES | 0 |
|
SU639236A1 |
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RU2197463C1 |
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METHOD OF PRODUCING GLYCERINE DICHLOROHYDRINS | 0 |
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SU789479A1 |
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RU2073647C1 |
METHOD OF PRODUCING EPICHLOROHYDRIN BY CHLORIC METHOD | 0 |
|
SU893986A1 |
METHOD FOR PREPARING TERTIARY-BUTYL CHLORIDE | 2004 |
|
RU2280636C1 |
METHOD FOR TREATMENT OF ORGANOCHLORINE MANUFACTURE WASTE FROM RESINIFICATION PRODUCTS | 2006 |
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RU2313513C1 |
Authors
Dates
2013-11-27—Published
2012-03-27—Filed