4H-BIS[1,2,5]OXADIAZOLO[3,4-b:3',4'-f]AZEPINE-8,9-DIAMINE DERIVATIVES AND METHOD FOR PRODUCTION THEREOF Russian patent published in 2013 - IPC C07D498/12 C07D223/14 C07D271/12 

FIELD: chemistry.

SUBSTANCE: invention relates to 4-R derivatives of 4H-bis[1,2,5]-oxadiazolo[3,4-b:3',4'-f]azepine-8,9-diamine of general formula (I), where R denotes H, an NH₂ group, an alkyl substitute or a substituted alkyl substitute. The compounds are obtained by reducing 7-R substituted derivatives of tris[1,2,5]oxadiazolo[3,4-b:3^',4^'-d:3",4"-f]azepine-1-oxide, where R denotes H, an NH₂ group, an alkyl substitute or a substituted alkyl substitute, with reducing agents selected from: hydrazine in free form, hydrazine in form of salts of hydrazine and mineral acids, hydrazine in form of salts of hydrazine and organic acids, hydrogen in the presence of a suitable reducing catalyst, known as a hydrogenating catalyst. The 4H-bis[1,2,5]oxadiazolo[3,4-b:3',4'-f]azepine-8,9-diamine derivatives are suitable for synthesis of annelated derivatives of imidazole, 1,2,3-triazole, pyrazine etc.

EFFECT: improved properties of the derivatives.

2 cl, 6 ex