FIELD: chemistry.
SUBSTANCE: method of producing a clay- and polymer-based nanocomposite includes the following steps: (a) contacting (I) a polymer solution in an organic solvent, (II) an aqueous clay suspension, (III) a modifier and (IV) a Bronsted acid to form an emulsion, said emulsion being formed either by providing a first mixture containing a polymer solution and a Bronsted acid, and a second mixture containing an aqueous clay suspension and a modifier, and combining the first and second mixtures, or by combining the polymer solution and the clay suspension first to form an emulsion and adding to said emulsion, separately or together, a modifier and a Bronsted acid; (b) mixing the emulsion to obtain a nanocomposite; and (c) separating the nanocomposite from the emulsion. Also disclosed is a polymer halogenation method, a nanocomposite, a composition for making articles and an article.
EFFECT: nanocomposites are characterised by low oxygen permeability and good clay retention.
13 cl, 11 tbl, 2 dwg, 24 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING NANOCOMPOSITES IN SEPARATE STREAMS | 2006 |
|
RU2421486C2 |
ELASTOMER NANOCOMPOSITES, NANOCOMPOSITE COMPOSITIONS AND METHODS FOR PRODUCTION THEREOF | 2011 |
|
RU2576596C2 |
COMPOSITES OF FUNCTIONALISED ISOBUTYLENE-INORGANIC CLAY POLYMER AND METHOD USING AQUEOUS-ORGANIC EMULSION | 2006 |
|
RU2430118C2 |
ELASTOMER COMPOSITE WITH FILLER AND METHOD OF REGULATING SIZE OF COMPOSITE GRAINS | 2013 |
|
RU2643557C2 |
GRAPHITE-CONTAINING NANOCOMPOSITES | 2009 |
|
RU2519403C2 |
ELASTOMERIC NANOCOMPOSITES, NANOCOMPOSITE COMPOSITIONS AND METHODS FOR PRODUCTION THEREOF | 2011 |
|
RU2592537C2 |
ELASTOMERIC NANOCOMPOSITES, NANOCOMPOSITE COMPOSITIONS AND METHODS FOR PRODUCTION THEREOF | 2010 |
|
RU2561170C2 |
GRAFTED POLYMERS INTENDED FOR DISPERSION OF GRAPHENE AND GRAPHITE | 2018 |
|
RU2759546C2 |
TRIETHYLAMINE-FUNCTIONALISED ELASTOMER USED IN PROTECTIVE MATERIAL | 2007 |
|
RU2448984C2 |
ELASTOMERIC NANOCOMPOSITES WITH PROCESS OILS ADDED | 2010 |
|
RU2559484C2 |
Authors
Dates
2013-12-10—Published
2008-10-14—Filed