FIELD: chemistry.
SUBSTANCE: invention relates to organoelemental spiro cyclic polymers. disclosed is a method of producing polyorganoelemento-spiro-cyclosiloxanes by co-hydrolysis of organoelemental comonomers: a compound of formula Z(OY)4, where Z=Si, Ti; Y=alkyl CnH2n+1(n=1-5) and diorganodialkoxysilane or diorganoalkoxysiloxane of general formula RO[SiRR'O]xR (R is Me or Et, R' is H or Me or Vin or Ph; x=1-4) in molar ratio of 1:(2-4) with a stoichiometric amount of water of 1-2 moles to the total amount of monomers without an organic solvent in the presence of an acid catalyst.
EFFECT: reducing consumption of crude components, environmental efficiency of the process, absence of ionic impurities in the end product and longer storage life thereof.
3 cl, 8 ex
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Authors
Dates
2014-02-20—Published
2012-12-21—Filed