FIELD: physics.
SUBSTANCE: invention relates to ion exchange. Disclosed is a method of producing an adaptively selective ion-exchange material, which involves preparing a template-containing phase, a monomer mixture, adding the monomer mixture to the prepared template-containing phase while stirring and raising temperature. The obtained granules are treated with a desorbing solution to form a porous cross-linked polymer with molecular imprints, having a cavity of given size. The molecular imprints are formed by forming chemical bonds between a rare-earth metal cation and functional groups of aminomethylene phosphinic acids formed by reacting urotropin, paraform and aqueous hypophosphorous acid solution.
EFFECT: high selectivity and sorption capacity with respect to rare-earth metal ions.
2 tbl, 1 dwg, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING COMPLEX-FORMING SORBENT FOR SELECTIVE EXTRACTION OF SUM OF RARE-EARTH METALS | 2018 |
|
RU2695064C1 |
METHOD OF OBTAINING SELECTIVE SORPTION AND ION-EXCHANGE MATERIALS | 2007 |
|
RU2325230C1 |
METHOD OF OBTAINING SORBENT FOR SELECTIVE EXTRACTION OF IODIDES | 2013 |
|
RU2560365C2 |
METHOD OF EXTRACTING RARE EARTH METALS FROM NITROPHOSPHATE SOLUTION IN NITRIC ACID PROCESSING OF APATITE CONCENTRATE | 2014 |
|
RU2559476C1 |
METHOD FOR SCANDIUM EXTRACTION FROM PRODUCTIVE SOLUTIONS | 2016 |
|
RU2613246C1 |
METHOD FOR PRODUCING SORBENT OF RARE-EARTH METALS | 2014 |
|
RU2579133C1 |
MOLECULARLY IMPRINTED POLYMER GRANULES FOR EXTRACTION OF LITHIUM, MERCURY AND SCANDIUM | 2017 |
|
RU2748350C2 |
METHOD OF EXTRACTING RARE EARTH ELEMENTS FROM EXTRACTION PHOSPHORIC ACID | 2013 |
|
RU2544731C2 |
GRANULES OF MOLECULARLY IMPRINTED POLYMERS FOR METAL EXTRACTION AND USE THEREOF | 2016 |
|
RU2719736C2 |
METHOD FOR SORPTION EXTRACTION OF RARE-EARTH ELEMENTS IN PRESENCE OF FLUORIDE IONS | 2023 |
|
RU2824510C1 |
Authors
Dates
2014-05-10—Published
2012-07-29—Filed