FIELD: chemistry.
SUBSTANCE: method includes determining intensity IA of the analytical line of the determined element A in the analysed material, calculating intensity IA2I in sample mixtures of the analysed material and a comparison sample with given content CBji of the determined element and comparing the intensity IA and IA2I quantitatively to obtain an estimate of the content CA of the determined element in the analysed material. Estimation of the content of the determined element in the analysed material is carried out in the order of determining first the intensity IA0 and content CA0 of the determined element in the comparison sample, as well as significant coefficients of influence of "interfering" elements contained in the analysed material on the intensity of the determined element in the material, experimentally determining intensities of analytical lines of "interfering" elements contained in the analysed material and the comparison sample, converting the intensities IA and IA0 of the determined element A in the analysed material and the comparison sample, respectively, by taking into account intensities and significant influence coefficients of "interfering" elements and quantitative comparison of converted intensities IAj and IA2I in the analysed material and calculation sample mixtures, respectively.
EFFECT: high accuracy of estimating content of an element.
5 tbl, 4 dwg
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PERFORMING HIGH PRECISION X-RAY SPECTROMETRY ANALYSIS OF NONHOMOGENEOUS MATERIALS | 1991 |
|
RU2054660C1 |
METHOD FOR MICRO-ARC OXIDATION | 2008 |
|
RU2389830C2 |
METHOD OF PLOTTING STABLE CALIBRATION CURVE WHEN DETERMINING QUANTITATIVE COMPOSITION OF ELEMENTS IN ZINC ALLOYS | 2011 |
|
RU2462701C1 |
METHOD FOR X-RAY FLUORESCENT ANALYSIS OF SAMPLES WITH UNDEFINED FILLER COMPONENTS | 2015 |
|
RU2594638C1 |
METHOD FOR CRYOLITE RATIO DETERMINATION FOR ELECTROLYTE WITH CALCIUM, MAGNESIUM AND POTASSIUM FLUORIDES ADDITIVES USING XRF METHOD | 2015 |
|
RU2616747C1 |
ROENTGEN-FLUORESCENT PROCEDURE FOR DETERMINATION OF CRYOLITE RATIO OF ELECTROLYTE | 2009 |
|
RU2424379C1 |
METHOD TO DETERMINE PARAMETERS OF INITIAL CONDITIONS OF NON-LINEAR TRAJECTORY OF AIR TARGET | 2011 |
|
RU2483272C2 |
METHOD OF DEVELOPMENT OF MULTI-DIMENSIONAL CALIBRATION MODELS OF ANALYTICAL INSTRUMENT | 2013 |
|
RU2541906C1 |
METHOD OF ROCKET LAUNCHING FOR MOBILE LAUNCHERS | 2012 |
|
RU2504725C2 |
METHOD OF CALIBRATING DOWNHOLE SPECTROMETERS | 2010 |
|
RU2422857C1 |
Authors
Dates
2014-07-27—Published
2013-05-16—Filed