FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing tetrabromophthalic anhydride via bromation of phthalic anhydride with molecular bromine in a medium of a concentrated inorganic acid in the presence of an oxidising agent while heating, wherein in order to simplify the process, the inorganic acid and oxidising agent used are 95-100% nitric acid, and the process is carried out at 45-70°C, followed by separation of the end product using known methods.
EFFECT: method lowers the process temperature and enables highly selective bromation.
2 cl, 1 tbl, 7 ex
Title | Year | Author | Number |
---|---|---|---|
PROCESS FOR PREPARING BROMINE-CONTAINING AROMATIC OR CONDENSED N- OR O-CONTAINING HETEROCYCLIC COMPOUNDS | 0 |
|
SU1817764A3 |
METHOD FOR PRODUCTION OF 6-BROM-2-AMINO-4-NITROPHENOL | 1991 |
|
RU2053223C1 |
METHOD FOR PRODUCTION OF 6-BROM-2,4-DINITROPHENOL | 1991 |
|
RU2053221C1 |
METHOD FOR PRODUCTION OF 6-BROM-2-AMINO-4-NITROPHENOL | 1991 |
|
RU2053222C1 |
METHOD OF 2-BROMINE-4,6-DINITROCHLOROBENZENE SYNTHESIS | 0 |
|
SU1770319A1 |
METHOD FOR PRODUCTION OF 6-BROM-2-AMINO-4-NITROPHENOL | 1992 |
|
RU2053224C1 |
METHOD OF PARALLEL OXIDATION OF SULFUR DIOXIDE AND ITS APPLICATION FOR PRODUCING TETRABROMPHTHALIC ANHYDRIDE | 2004 |
|
RU2351536C2 |
PROCESS FOR PREPARING AROMATIC 2-BROMOSUBSTITUTED DIAZO CONSTITUENTS | 1989 |
|
RU1804079C |
METHOD FOR PRODUCTION OF 1,2-DIBROM-3,5-DINITROBENZENE | 1991 |
|
RU2053220C1 |
METHOD OF SYNTHESIS OF 2-BROMO-4,6-DINITROANILINE | 1991 |
|
RU2030391C1 |
Authors
Dates
2014-08-27—Published
2013-03-21—Filed