FIELD: chemistry.
SUBSTANCE: invention relates to a method of obtaining 3-pyridinyl-1,5,3-dithiazepinanes of formula I. The essence of the method consists in the interaction of respective N,N-bis(methoxymethyl)-N-pyridinamine with 1,2-ethanedithiol in the presence of the catalyst CuCl2 in a molar ratio N-bis(methoxymethyl)-N-pyridinamine: 1,2-ethanedithiol: CuCl2=10:10:(0,3-0,7) at room temperature and atmospheric pressure in chloroform for 120-150 minutes. The output of respective 3-pyridinyl-1,5,3-dithiazepinanes of general formula (1) constitutes 68-89% (a); (b); (c); (d).
EFFECT: improvement of the method.
1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF OBTAINING 3-HETARYL-1,5,3-DITHIAZEPINANES | 2012 |
|
RU2529502C2 |
METHOD OF OBTAINING 3-PYRIDINYL-1,5,3-DITHIAZOCINANES | 2012 |
|
RU2536231C2 |
METHOD OF OBTAINING 3-HETARYL-1,5,3-DITHIAZOCINANES | 2012 |
|
RU2536261C2 |
METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES | 2011 |
|
RU2466997C1 |
METHOD OF PRODUCING N-(1,5,3-DITHIAZEPINAN-3-YL)AMIDES | 2011 |
|
RU2481338C1 |
METHOD OF PRODUCING α,ω -BIS-(1,5,3-DITHIAZEPINAN-3-YL)ALKANES | 2011 |
|
RU2478634C2 |
METHOD OF PRODUCING N-(1,5,3-DITHIAZEPAN-3-YL)AMIDES | 2011 |
|
RU2478626C1 |
METHOD OF PRODUCING N-CYCLOALKYL-SUBSTITUTED 1,5,3-DITHIAZEPANES | 2015 |
|
RU2601313C1 |
METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES | 2013 |
|
RU2536132C2 |
METHOD FOR OBTAINING 3- AND 4-(1,5,3-DITHIAZACYCLOALKAN-3-YL)BENZAMIDES | 2014 |
|
RU2574073C2 |
Authors
Dates
2014-11-20—Published
2012-10-25—Filed