FIELD: chemistry.
SUBSTANCE: invention relates to field of organic chemistry, in particular to method of obtaining 3-hetaryl-1,5,3-dithiazepinanes of general formula (1) 
, where 
; 
; 
; 
; 
; 
; 
; 
; 
, consisting in the following: N1,N1,N6,N6-tetramethyl-2,5-dithiahexane-1,6-diamine is subjected to interaction with hetarylamine [2-pyridinamine, 3-pyridinamine, 5-bromo-2-pyridinamine, 5-methyl-2-pyridinamine, 4-pyridinylmethylamine, 5-nitro-1,3-thiazol-2-amine, 6-nitro-1,3-benzothiazol-2-amine, 2-91h-indol-3-yl)-1-ethanamone, 5-methyl-1H-pyrazol-3-amine] in presence of catalyst CuCl2 in molar ratio N1,N1,N6,N6-tetramethyl-2,5-dithiahexane-1,6-diamine:hetarylamine: CuCl2=10:10:(0.3-0.7) at temperature 55-65°C and atmospheric pressure in chloroform as solvent for 50-80 minutes.
EFFECT: elaborated is method of obtaining 3-hetaryl-1,5,3-dithiazepinanes, which can be applied as biologically active substances.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF OBTAINING 3-HETARYL-1,5,3-DITHIAZOCINANES | 2012 |
|
RU2536261C2 |
| METHOD OF OBTAINING 3-PYRIDINYL-1,5,3-DITHIAZEPINANES | 2012 |
|
RU2532923C2 |
| METHOD FOR OBTAINING 3- AND 4-(1,5,3-DITHIAZACYCLOALKAN-3-YL)BENZAMIDES | 2014 |
|
RU2574073C2 |
| METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES | 2013 |
|
RU2536149C2 |
| METHOD OF OBTAINING 3-(1-ADAMANTYL)- AND 3-[1-(1-ADAMANTYL)ETHYL]-1,5,3-DITHIAZEPINANES | 2013 |
|
RU2551668C1 |
| METHOD OF PRODUCING N-(1,5,3-DITHIAZEPAN-3-YL)AMIDES | 2011 |
|
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|
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| METHOD OF OBTAINING 3,3'-(3,6-DIOXAOCTANE-1,8-DIYL)BIS-1,5,3-DITHIAZEPINANE AND ITS APPLICATION AS AGENT WITH FUNGICIDAL ACTIVITY | 2013 |
|
RU2547267C2 |
| METHOD OF OBTAINING 3-PYRIDINYL-1,5,3-DITHIAZOCINANES | 2012 |
|
RU2536231C2 |
| METHOD OF PRODUCING N-CYCLOPENTYL-SUBSTITUTED 1,5,3-DITHIAZEPANES | 2014 |
|
RU2565790C1 |
