METHOD OF PREPARING CATALYST FOR HYDROPURIFICATION OF HYDROCARBON RAW MATERIAL Russian patent published in 2014 - IPC B01J37/02 B01J21/04 B01J29/89 B01J23/882 B01J23/883 B01J31/16 C10G45/08 

Abstract RU 2534997 C1

FIELD: chemistry.

SUBSTANCE: method of preparing catalyst for purification of hydrocarbon raw material includes into composition cobalt, nickel, molybdenum, aluminium and silicon. Two bimetal complex compounds [Co(H2O)x(L)y]2[Mo4O11(C6H5O7)2] and [Ni(H2O)x(L)y]2[Mo4O11(C6H5O7)2], where L is partly deprotonated form of citric acid C6H6O7; x=0 or 2; y=0 or 1, are simultaneously applied on carrier, containing aluminium oxide and amorphous alumosilicate. After that, catalyst is dried with obtaining catalyst, containing components in the following concentrations, wt %: in total [Co(H2O)x(L)y]2[Mo4O11(C6H5O7)2] and [Ni(H2O)x(L)y]2[Mo4O11(C6H5O7)2] - 24.5-39.0; including [Co(H2O)x(L)y]2[Mo4O11(C6H5O7)2] - 6.2-29.5; [Ni(H2O)x(L)y]2[Mo4O11(C6H5O7)2] - 6.2-29.5; amorphous alumosilicate - 5.9-37.8; γ-Al2O3 - the remaining part. It corresponds to content in annealed at 550°C catalyst, wt %: MoO3 - 14.0-24.0; in total CoO+NiO - 3.6-6.0; including CoO - 0.9-4.5; NiO - 0.9-4.5; amorphous alumosilicate- 6.7-42.0; Al2O3 - the remaining part.

EFFECT: method makes it possible to obtain catalyst, which has maximal activity in target reactions, taking place in the process of hydropurification of hydrocarbon raw material, and provides obtaining petroleum products with low content of sulphur.

7 cl, 1 tbl, 8 ex

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RU 2 534 997 C1

Authors

Klimov Oleg Vladimirovich

Korjakina Galina Ivanovna

Leonova Ksenija Aleksandrovna

Budukva Sergej Viktorovich

Perejma Vasilij Jur'Evich

Dik Pavel Petrovich

Noskov Aleksandr Stepanovich

Dates

2014-12-10Published

2013-09-27Filed