FIELD: chemistry.
SUBSTANCE: described is catalyst including into its composition cobalt, nickel, molybdenum, aluminium and silicon, with cobalt, nickel and molybdenum contained in form of bimetal complex compounds [Co(H2O)x(L)y]2[Mo4O11(C6H5O7)2] and [Ni(H2O)x(L)y]2[Mo4O11(C6H5O7)2], where L is partly deprotonated form of citric acid C6H6O7; x=0 or 2; y=0 or 1; silicon in form of amorphous alumosilicate, aluminium in form of γ-Al2O3 and amorphous alumosilicate. Components in catalyst are contained in the following concentrations, wt %: in total [Co(H2O)x(L)y]2[Mo4O11(C6H5O7)2] and [Ni(H2O)x(L)y]2[Mo4O11(C6H5O7)2] - 24.5-39.0; including [Co(H2O)x(L)y]2[Mo4O11(C6H5O7)2] - 6,2-29,5; [Co(H2O)x(L)y]2[Mo4O11(C6H5O7)2] - 6,2-29,5; amorphous alumosilicate- 5.9-37.8; γ-Al2O3 -the remaining part, which corresponds to content in annealed at 550°C catalyst, wt %: MoO3 - 14.0-24.0; in total CoO+NiO - 3.6-6.0; including CoO - 0.9-4.5; NiO - 0.9-4.5; amorphous alumosilicate- 6.7-42.0; Al2O3 - the remaining part.
EFFECT: obtaining catalyst, which has maximal activity activity in target reactions, taking place in the process of hydropurification of hydrocarbon raw material.
4 cl, 3 tbl, 8 ex
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Authors
Dates
2014-12-10—Published
2013-09-27—Filed