FIELD: chemistry.
SUBSTANCE: invention relates to a method of preparing a catalyst for hydrocracking hydrocarbon material, including nickel, molybdenum, aluminium and silicon. Method involves preparation of a granular support, containing aluminium oxide and 50–80 wt% amorphous aluminium silicate with weight ratio Si/Al from 0.6 to 0.85, application on produced granulated support of bimetallic complexes [Ni(H2O)x(L)y]2[Mo4O11(C6H5O7)2], where L is a partially deprotonated form of citric acid C6H5O7; x = 0 or 2; y = 0 or 1, drying catalyst at temperature 100–250 °C. Components in obtained catalyst are in following concentrations, wt%: [Ni(H2O)x(L)y]2[Mo4O11(C6H5O7)2] – 13.1–23.3; amorphous aluminum silicate – 40.0–61.3; γ-Al2O3 - balance, which corresponds to content in catalyst annealed at 550°C, wt%: MoO3 – 7.0–13.0; NiO – 1.8–3.4; amorphous aluminum silicate – 43.1–66.9; γ-Al2O3 – balance.
EFFECT: technical result is use of a catalyst in hydrocracking which is prepared using disclosed method, ensures production of diesel fraction with high output.
4 cl, 1 tbl, 6 ex
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RU2626397C1 |
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RU2534997C1 |
HYDROCARBONS CRUDE HYDROCRAKING CATALYST | 2016 |
|
RU2626396C1 |
Authors
Dates
2017-01-11—Published
2015-11-05—Filed