FIELD: chemistry.
SUBSTANCE: invention relates to method of obtaining 4-amino-5-fluoro-3-halogen-6-(substituted)picolinate of formula I , where W represents Cl, Br or I; R represents C1-C4 alkyl, cyclopropyl, C2-C4 alkenyl or phenyl, substituted with 1-4 substituents, independently selected from halogen, C1-C4 alkyl, C1-C4 halogenalkyl, C1-C4 alkoxy or C1-C4 halogenalkoxy; and R1 represents C1-C12 alkyl or non-substituted C7-C11 arylalkyl; which includes the following stages: fluorine exchange, amination, halogen exchange, halogenation and binding by means of transition metal.
EFFECT: method improvement.
7 cl, 6 ex
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Authors
Dates
2015-03-27—Published
2012-01-24—Filed