DIPHOSPHINES, CATALYST OF SYNTHESIS OF THEREOF-BASED ESTERS AND METHOD OF ESTER SYNTHESIS IN ITS PRESENCE Russian patent published in 2015 - IPC C07F9/50 

Abstract RU 2540079 C2

FIELD: chemistry.

SUBSTANCE: group of inventions relates to diphosphines, palladium catalyst based on them and method of ester synthesis with application of said catalyst, which can be used in chemical industry, with diphosphine having formula: , where R1, R2 = H, Alk, Ar, OR, excluding case R1, R2 = H. Method of ester synthesis is realised by mixing in solvent medium alkene, CO and alcohol with addition of said diphosphine and palladium.

EFFECT: increased degree of reagent conversion with reduction of consumption of expensive diphosphines for ester synthesis.

7 cl, 2 tbl, 16 ex

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Authors

Nifant'Ev Il'Ja Ehduardovich

Tavtorkin Aleksandr Nikolaevich

Aver'Janov Vjacheslav Aleksandrovich

Batashev Sergej Aleksandrovich

Sevost'Janova Nadezhda Tengizovna

Dates

2015-01-27Published

2013-03-06Filed