FIELD: chemistry.
SUBSTANCE: catalyst for producing synthetic base oils during oligomerisation of decene-1 contains chromium oxide as an active component and, as a support, silica gel and zirconium oxide or cerium oxide, with the following ratio of components, wt %: chromium oxide 1-3, support - the balance. The catalyst is obtained by preparing a support by impregnating silica gel with particle size of 0.2-0.4 mm with an aqueous solution of zirconium oxonitrate ZrO(NO3)2·6H2O or cerium nitrate Ce(NO3)3·6H2O, drying at room temperature for 2-2.5 hours and then at 100-110°C for 15-30 minutes and calcining in an air current at 500-550°C for 4.5-5 hours. Chromium is deposited on the obtained support by impregnating with an organic solution a chromium salt. The catalyst is dried at room temperature for 2-3 hours and then at 120-130°C for 2-2.5 hours. The obtained support is characterised by a high specific surface area of 700-723 m2/g and pore volume of 2.1 cm3/g.
EFFECT: invention provides high catalytic activity and service life of the catalyst, significantly improves the quality of the obtained synthetic base oil with a high viscosity index and low chilling point.
2 cl, 1 tbl, 9 ex
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Authors
Dates
2015-02-10—Published
2014-01-29—Filed