FIELD: chemistry.
SUBSTANCE: method includes mixing tetraethyl orthosilicate and chromium nitrate nanohydrate, followed by adding the mixture to 0.28 M HCl solution with pH 5.2-5.5; mixing the solution for 2-3 hours at room temperature and adding to a solution containing Pluronic 123 surfactant in 0.28 M HCl with pH 5.2-5.5; mixing the obtained mixture at 40-45°C for 3-4 hours; holding in an autoclave with a teflon insert at 110-120°C for 10-12 hours; separating the solid product by filtering; drying at 100-120°C for 2-3 hours and annealing in an air current at 500-550°C for 4-5 hours. The obtained catalyst is characterised by a high specific surface area of 723 m2/g, pore volume of 2.154 cm3/g and average pore diameter of 117 E.
EFFECT: invention provides high catalytic activity, which enables to obtain synthetic base oil with a high viscosity index and low chilling point with high conversion of decene-1.
1 tbl, 9 ex
Title | Year | Author | Number |
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METHOD OF PRODUCING SYNTHETIC BASE OILS | 2014 |
|
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RU2334554C2 |
CATALYST FOR OBTAINING SYNTHETIC BASIC OILS IN PROCESS OF ETHYLENE COOLIGOMERISATION WITH C6-C10 ALPHA-OLEFINS AND METHOD OF PREPARING THEREOF | 2013 |
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CATALYST FOR OLIGOMERISATION OF ALPHA-OLEFINS, METHOD OF PRODUCING SAID CATALYST AND METHOD FOR OLIGOMERISATION OF ALPHA-OLEFINS | 2011 |
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Authors
Dates
2015-10-20—Published
2014-10-15—Filed