FIELD: chemistry.
SUBSTANCE: claimed is method of obtaining Si-containing bis-(endo-bicyclo[4.2.1]nona-2,4,7-trienes) by interaction of Si-containing α,ω-diacetylenes with 1,3,5-cycloheptatriene in presence of catalytic system TiCl4-Et2AlCl at temperature 20-80°C, in benzene for 14-48 h. Method makes it possible to obtain individual Si-containing bis-(endo-bicyclo[4.2.1]nona-2,4,7-trienes), which can be components of high energy fuels for air-reactive rocket systems and products in synthesis of a number of medications.
EFFECT: increased output.
1 tbl, 10 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING Si-CONTAINING BIS-(ENDO-BICYCLO[4,2,1]NONE-2,4,7-TRIENES) | 2013 |
|
RU2541530C1 |
| METHOD OF PRODUCING Si-CONTAINING BICYCLO[4,2,1]NONA-2,4,7-TRIENES | 2013 |
|
RU2559365C2 |
| METHOD OF PRODUCING SI-CONTAINING BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTITUMOUR ACTIVITY | 2018 |
|
RU2726195C2 |
| METHOD OF OBTAINING BIS-(ENDO-BICYCLO[4,2,1]NONE-2,4-DIENES) | 2013 |
|
RU2556007C2 |
| METHOD FOR COMBINED PRODUCTION OF 1-HYDROXYMETHYL-SUBSTITUTED BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTINEOPLASTIC ACTIVITY | 2019 |
|
RU2735661C1 |
| METHOD FOR COMBINED PRODUCTION OF 1-METHYL-SUBSTITUTED BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTITUMOUR ACTIVITY | 2019 |
|
RU2735663C1 |
| METHOD OF PRODUCING N-CONTAINING BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTITUMOUR ACTIVITY | 2019 |
|
RU2735662C1 |
| METHOD OF PRODUCING BICYCLO[4,2,1]NONA-2,4-DIENES | 2013 |
|
RU2551278C1 |
| DISPLACED 9-AZABICYCLO[4.2.1]NONA-2,4,7-TRIENES, METHOD OF SYNTHESIS THEREOF AND APPLICATION THEREOF AS ANTITUMORALLY ACTIVE PRODUCTS | 2020 |
|
RU2751350C1 |
| METHOD OF PRODUCING (E)-BICYCLO[4,2,2]DECA-2,4,7-TRIENES | 2015 |
|
RU2605428C2 |
