FIELD: chemistry.
SUBSTANCE: invention relates to method of obtaining bis-(endo-bicyclo[4.2.1]none-2,4-dienes) of general formula (1), n = 0, 1, 2, 4. α,ω-diallenes of general formula interact with 1,3,5-cycloheptatriene (CHT) in presence of catalytic system TiCl4-Et2AlCl, with molar ratio α,ω-diallene:CHT:TiCl4:Et2AlCl = (9-11):20:(0.1-0.3):4, temperature 20-80°C, in benzene, for 10-48 h.
EFFECT: application of claimed invention makes it possible to obtain target compounds.
11 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING BICYCLO[4,2,1]NONA-2,4-DIENES | 2013 |
|
RU2551278C1 |
METHOD OF PRODUCING Si-CONTAINING BIS-(ENDO-BICYCLO[4,2,1]NONE-2,4,7-TRIENES) | 2013 |
|
RU2541530C1 |
METHOD OF OBTAINING Si-CONTAINING BIS-(ENDO-BICYCLO[4.2.1]NONA-2,4,7-TRIENES) | 2013 |
|
RU2541792C1 |
METHOD OF PRODUCING N-CONTAINING BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTITUMOUR ACTIVITY | 2019 |
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RU2735662C1 |
METHOD OF PRODUCING SI-CONTAINING BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTITUMOUR ACTIVITY | 2018 |
|
RU2726195C2 |
METHOD OF PRODUCING Si-CONTAINING BICYCLO[4,2,1]NONA-2,4,7-TRIENES | 2013 |
|
RU2559365C2 |
METHOD FOR COMBINED PRODUCTION OF 1-HYDROXYMETHYL-SUBSTITUTED BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTINEOPLASTIC ACTIVITY | 2019 |
|
RU2735661C1 |
METHOD FOR COMBINED PRODUCTION OF 1-METHYL-SUBSTITUTED BICYCLO[4_2_1]NONA-2,4,7-TRIENES EXHIBITING ANTITUMOUR ACTIVITY | 2019 |
|
RU2735663C1 |
METHOD OF PRODUCING (E)-BICYCLO[4,2,2]DECA-2,4,7-TRIENES | 2015 |
|
RU2605428C2 |
SUBSTITUTED (E)-9-AZABICYCLO[4.2.1]NONA-2,4-DIENES, METHOD FOR THEIR PREPARATION AND USE AS ANTICANCER DRUGS | 2020 |
|
RU2751352C1 |
Authors
Dates
2015-07-10—Published
2013-11-06—Filed