FIELD: chemistry.
SUBSTANCE: invention relates to preparation of a rubber composition based on hydrogenated butadiene-nitrile rubber with high content of acrylonitrile and low unsaturation and can be used in the rubber and industrial rubber industry to produce multilayer rubber-cord articles, used in conditions with dynamic loads, fuels and oils at high temperatures for a long period of time. The technical result is achieved by using, in the formulation of the rubber composition, a polymer base in the form of hydrogenated butadiene-nitrile rubber with high content of acrylonitrile (49-50%) and low unsaturation (5-7%), a vulcanising agent - sulphur donor in the form of N,N'-dithiodimorpholine, coupled with a dual system of high-activity vulcanisation accelerators, with the following ratio of components, pts.wt: hydrogenated butadiene-nitrile rubber with high content of acrylonitrile of 49-50% and low unsaturation (5-7%) - 100.0; ground sulphur - 0.1-0.3; technical carbon - 40.0-50.0; zinc oxide - 5.0-8.0; white soot - 5.0-20.0; plasticiser - 10.0-18.0; stearic acid - 0.5-1.5; diaphene FP-n/b 2.0; acetonanyl N - n/b 1.0; N,N'-dithiodimorpholine - 0.5-2.0; thiuram D - 0.6-1.5; sulphenamide C - 0.8-2.0. The invention increases oil and heat resistance and dynamic endurance of multilayer rubber-cord articles.
EFFECT: obtaining a rubber composition with high oil and heat resistance, high dynamic endurance, which enables rubber-cord articles to retain operational properties in aggressive media at high temperatures for a long period of time.
2 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| ELASTOMERIC COMPOSITION | 2018 |
|
RU2680508C1 |
| OIL-AND-PETROL-RESISTANT AND COLD-RESISTANT RUBBER MIXTURE | 2018 |
|
RU2688741C1 |
| OIL-HEAT-RESISTANT ELASTOMERIC COMPOSITION | 2019 |
|
RU2714351C1 |
| RUBBER-CORD COMPOSITE | 2011 |
|
RU2481956C2 |
| VULCANIZABLE RUBBER MIXTURE ON THE BASIS OF THE HYDROGENATED BUTADIENE-NITRILE CAOUTCHOUCK | 2005 |
|
RU2304596C2 |
| POLYMER COMPOSITION | 2009 |
|
RU2443731C2 |
| OIL-RESISTANT RUBBER-CORD COMPOSITE | 2015 |
|
RU2645479C2 |
| COMPOSITE MATERIAL BASED ON HYDROGENATED BUTADIENE-NITRILE RUBBER AND ACRYLIC RUBBER | 2011 |
|
RU2492193C2 |
| ELASTOMER COMPOSITION | 2022 |
|
RU2786014C1 |
| ANTIFOULING RUBBER COMPOSITION | 2023 |
|
RU2811806C1 |
Authors
Dates
2015-04-10—Published
2013-07-09—Filed