FIELD: electricity.
SUBSTANCE: according to the invention for the purpose of manufacturing of active electrode mass gel-polymer electrolyte based on butadiene-nitrile rubber and its copolymers or polyacrylate or styrol and acrylate copolymer is used as a binding agent. Mixing of components is carried out simultaneously with ultrasonic material dispersion. With the following ratio of the mixture components, % (dry weight): active material - 76-96; acetylene carbon black - 0.1-12, gel-polymer electrolyte based on butadiene-nitrile rubber and its copolymers or polyacrylate or styrol and acrylate copolymer - 4-12, and drying of electrodes is made till residual moisture is equal to 0.001%. Gel-polymer or solid polymer electrolytes of variable composition are used as electroconductive and binding agent. The following substances are used as a plasticising agent for gel-polymer electrolyte: propylene carbonate, dimethyl carbonate, diethyl carbonate, and their mixtures with ethylene carbonate; the following substances are used as ionogenic lithium salt: LiPF6, LiClO4, LiBF4, LiAsF6; material of the negative electrode may include natural or synthetic graphites, material of the negative electrode may include LiFePO4, LiCoO2, LiNiO2.
EFFECT: increased specific discharge capacity, reduced ecological risk and improved explosion safety.
2 tbl, 5 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR MANUFACTURING OF LITHIUM-ION ACCUMULATOR ELECTRODES | 2008 |
|
RU2390078C1 |
PREPARATION METHOD OF GEL ELECTROLYTE FOR LITHIUM-ION CELLS | 2009 |
|
RU2414777C1 |
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|
RU2564201C1 |
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RU2216825C2 |
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RU2621310C2 |
SOLID POLYMER ELECTROLYTE FOR LITHIUM SOURCES OF CURRENT | 2012 |
|
RU2503098C1 |
ANODE FOR ACCUMULATOR OF LITHIUM-ION BATTERY, METHOD OF ITS MANUFACTURING AND BATTERY CONTAINING IT | 2013 |
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RU2616614C2 |
ACCUMULATOR BATTERY WITH NON-AQUEOUS ELECTROLYTE | 2012 |
|
RU2574592C2 |
Authors
Dates
2015-04-10—Published
2014-04-03—Filed