FIELD: chemistry.
SUBSTANCE: regeneration includes oxidation of deactivated catalyst by supply of air into reactor zone at rate 500-2000 h-1, heating to temperature 200-270°C at heating rate 1-3°C/min and exposure at said temperature in air flow for 1-5 h. Further reduction is carried out by supply of hydrogen-containing gas at oxidation temperature with volume rate 1000-5000 h-1, heating to temperature 300-600°C at rate 1-5°C/min and exposure at heating temperature in flow of hydrogen-containing gas for 1-5 h. Method includes carrying out additional stage of deactivated catalyst reduction with hydrogen-containing gas before redox regeneration. Hydrogen-containing gas of the similar composition with hydrogen content from 20 to 100 vol % is used in reduction.
EFFECT: increased efficiency of regeneration and increase of catalyst service duration in comparison with other methods known in technology.
4 cl, 1 tbl, 7 ex
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Authors
Dates
2015-06-10—Published
2014-04-02—Filed