FIELD: chemistry.
SUBSTANCE: method involves: a first step for activation treatment of particles of a supported cobalt-based Fischer-Tropsch synthesis catalyst precursor, having a catalyst support saturated with cobalt, a hydrogen-containing reducing gas or a nitrogen-containing gas at a first heating rate HR1 until temperature of the precursor reaches a value T1, where 80°C≤T1≤180°C, to form a partially treated catalyst precursor; a second step for activation treatment of the partially treated catalyst precursor with a hydrogen-containing reducing gas at a second heating rate HR2 with step x, where x is an integer greater than 1 and 0≤HR2<HR1, wherein the precursor is heated from temperature T1 to temperature TH, where TH>T1 and TH<200°C for a time t1, where t1 is equal to 0.1-20 hours, to form a partially reduced catalyst precursor; and then a third step for activation treatment of the partially reduced catalyst precursor with a hydrogen-containing reducing gas at a third heating rate HR3, where HR3>HR2, until temperature of the partially reduced catalyst precursor reaches a value T2, where 300°C≤T2≤600°C and holding the partially reduced catalyst precursor at T2 for a time t2, where t2 is such that 0<t2≤20 hours, to form an activated supported cobalt-based Fischer-Tropsch synthesis catalyst.
EFFECT: obtaining a high-activity catalyst.
10 cl, 1 tbl, 1 ex
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Authors
Dates
2012-08-10—Published
2008-05-05—Filed