METHOD OF PRODUCING 4,18,32-TRIS(o,m,p-HALOPHENYL)-11,25,39-TRIOXA-2,6,16,20,30,34-HEXATHIA-4,18,32-TRIAZAHEPTACYCLO[38.2.2.2.2.2.2.2]TETRAPENTACONTA-1(43),7(54),8,10(53),12(52),13,15(51),21(50),22,24(49),26(48),27,29(47),35(46),36,38(45),40,41-OCTADECAENES Russian patent published in 2015 - IPC C07C15/00 

FIELD: chemistry.

SUBSTANCE: invention relates to a method of producing 4,18,32-tris(o,m,p-halophenyl)-11,25,39-trioxa-2,6,16,20,30,34-hexathia-4,18,32-triazaheptacyclo[38.2.2.2^7,10.2^12,15.2^21,24.2^26,29.2^35,38]tetrapentaconta-1(43),7(54),8,10(53),12(52),13,15(51),21(50),22,24(49),26(48),27,29(47),35(46),36,38(45),40,41-octadecaenes, which includes reacting N,N-bis(methoxymethyl)-N-aryl(o-chlorophenyl, m-chlorophenyl, m-fluorophenyl, m-bromophenyl, p-bromophenyl)amines with 4,4'-dimercaptodiphenyl oxide in the presence of a samarium nitrate crystalline hydrate Sm(NO₃ ) ₃*6H₂O catalyst, taken in molar ratio N,N-bis(methoxymethyl)-N-arylamine : 4,4'-dimercaptodiphenyl oxide : Sm(NO₃)₃*6H₂O=1:1:0.05, at room temperature (about 20°C) and atmospheric pressure in ethyl acetate as a solvent for 6-8 hours. The output of the corresponding 4,18,32-tris(o,m,p-halophenyl)-11,25,39-trioxa-2,6,16,20,30,34-hexathia-4,18,32-triazaheptacyclo[38.2.2.2^7,10.2^12,15.2^21,24.2^26,29.2^35,38]tetrapentaconta-1(43),7(54),8,10(53),12(52),13,15(51),21(50),22,24(49),26(48),27,29(47),35(46),36,38(45),40,41-octadecaenes of general formula (1) is 68-85%.

EFFECT: high output.

1 tbl, 1 ex