FIELD: chemistry.
SUBSTANCE: invention relates to method of obtaining water-absorbing polymer particles by polymerisation of monomer solution drips. Monomer solution contains at least one ethylene-unsaturated monomer, which has acid groups and can be at least partly neutralised; at least one cross-linking agent; at least one initiator and water. Polymerisation includes passing concurrent gas flow through polymerisation chamber. Temperature of gas, leaving polymerisation chamber, constitutes 130°C or lower. Temperature of gas inside polymerisation chamber constitutes at least 0.5 m/s. Drips are created by means of drip-forming plate. Distance between plate holes constitutes from 10 to 50 mm. Also described are water-absorbing, agglomerated polymer particles, liquid-absorbing products.
EFFECT: obtaining water-absorbing polymer particles with higher bulk density, narrow distribution of values of particle diameter, several smaller planes instead one big plane, excellent mechanical stability, as well as excellent dosing properties.
17 cl, 10 dwg, 21 tbl, 25 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING MECHANICALLY STABLE WATER-ABSORBENT POLYMER PARTICLES | 2007 |
|
RU2471812C2 |
PROCESS FOR PRODUCING SURFACE-POSTCROSSLINKED WATER-ABSORBENT POLYMER PARTICLES | 2013 |
|
RU2653056C2 |
METHOD OF PRODUCING WATER-ABSORBING POLYMER PARTICLES WITH HIGH PERMEABILITY BY POLYMERISING DROPLETS OF MONOMER SOLUTION | 2007 |
|
RU2463309C2 |
METHOD OF PRODUCING WATER-ABSORBING POLYMER PARTICLES WITH HIGH PERMEABILITY BY POLYMERISING DROPLETS OF MONOMER SOLUTION | 2007 |
|
RU2464284C2 |
METHOD OF PRODUCING ADDITIONALLY CROSS-LINKED WATER-ABSORBING POLYMER PARTICLES WITH HIGH ABSORPTION BY POLYMERISING DROPLETS OF SOLUTION | 2007 |
|
RU2480481C2 |
SUPERABSORBENT POLYMERS CAPABLE OF FAST ABSORPTION AND SYNTHESIS METHOD THEREOF | 2012 |
|
RU2586214C2 |
METHOD OF PRODUCING WATER-ABSORBENT POLYMER PARTICLES BY POLYMERISATION OF DROPLETS OF MONOMER SOLUTION | 2008 |
|
RU2484100C2 |
POLYMERS PRODUCING HYDROGEL AND ABSORBING AQUEOUS LIQUIDS, PRODUCTION METHOD AND APPLICATION OF MONOETHYLENOID-NONSATURATED C-C-CARBOXYLIC ACIDS CONTAINING α-TOCOPHEROL AS STABILISING ADDITIVE | 2002 |
|
RU2329066C9 |
POWDER-LIKE POLYMERIC PRODUCT AND ARTICLES MADE OF THIS PRODUCT | 2000 |
|
RU2322465C2 |
ABSORBENT ARTICLE WITH PROFILED ACQUISITION-DISTRIBUTION SYSTEM | 2013 |
|
RU2650061C2 |
Authors
Dates
2015-09-20—Published
2010-09-02—Filed