FIELD: chemistry.
SUBSTANCE: invention relates to method of obtaining 6-(m,n-halogenphenyl)-1,11-dioxa-4,8-dithia-6-azacyclotridecanes of general formula (1): 
R=m-Cl, n-Cl, m-Br, n-Br, m-F, n-F, in which N,N-bis(methoxymethyl)-N-aryl(m-chlorophenyl, n-chlorophenyl, m-bromophenyl, n-bromophenyl, m-fluorophenyl, n-fluorophenyl)amines are subjected to interaction with 3,6-dioxa-1,8-octanedithiol in presence of catalyst CuCl with molar ratio of N,N-bis(methoxymethyl)-N-arylamine:3,6-dioxa-1,8-octanedithiol:CuCl=1:1:(0.03-0.07) in methylene chloride as solvent, at room temperature (~20°C) and atmospheric pressure for 6-8 h.
EFFECT: obtaining compound with high output.
1 tbl, 1 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD FOR OBTAINING 6-CYCLOALKYL-1,11-DIOXA-4,8-DITHIA-6-AZACYCLOTRIDECANES | 2017 |
|
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| METHOD FOR PRODUCING ALKYL 2-(1,11-DIOXA-4,8-DITHIA-6-AZACYCLOPENTADECAN-6-YL)ALKANOATES | 2016 |
|
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|
RU2640211C2 |
| METHOD FOR PRODUCING (1,11-DIOXA-4,8-DITHIA-6-AZACYCLOTHRENEDECAN-6-YL) -QUINOLINES | 2016 |
|
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| METHOD OF PRODUCING N-ARYL-1,5,3-DITHIAZONANES | 2014 |
|
RU2559361C1 |
| (3bR*,7aR*,10bR*,14aR*-cis-14c,14d)-2,9 BIS(HALOGENPHENYL)OCTADECAHYDRO-1H,8H-2,3a,7b,9,10a,14b-HEXAAZADIBENZO[fg,op]TETRACENES AND THEIR PRODUCTION METHOD | 2021 |
|
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| METHOD OF PRODUCING 4-(O,M,P-HALOGENPHENYL)-2,6-DITHIA-4-AZABICYCLO [5,3,1]UNDECA-1(11),7,9-TRIENES | 2016 |
|
RU2626006C1 |
| METHOD FOR PRODUCING 3-(O,M,N-HALOGENPHENYL)-3,4-DIHYDRO-2H-BENZO[F][1,5,3]DITHIAZEPINES | 2016 |
|
RU2632661C2 |
| METHOD OF PRODUCING 6-HALOGENPHENYL-2,4,8-TRITHIA-6-AZA-1,3(1,4)-DIBENZOCYCLOOCTAPHANS | 2015 |
|
RU2605430C1 |
| METHOD OF OBTAINING 3-HETARYL-1,5,3-DITHIAZOCINANES | 2012 |
|
RU2536261C2 |
