FIELD: chemistry.
SUBSTANCE: invention relates to highly molecular compounds and deals with method of obtaining acryl and methacryl polymers, which are applied in obtaining composite materials, coatings and paint-and-varnish products. Method of obtaining acryl and methacryl polymers is realised by polymerisation of monomer in solution of polar organic solvent, which does not contain mobile halogen atom, in presence of organic initiator, containing mobile halogen atom, organic ligand, which contains 2 or more nitrogen atoms, and catalyst, based on metal of group 11 of Periodic system of elements, with method being characterised by the fact that as metal of group 11 silver is used, applied in form of mirror on internal surface of reaction vessel and/or on external surface of substrate, placed in reaction system.
EFFECT: method makes it possible to increase specific rate of polymerisation (ie polymerisation rate related to unit of catalysts weight) of acryl and methacryl monomers.
8 ex
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Authors
Dates
2015-10-20—Published
2014-07-01—Filed