FIELD: chemistry.
SUBSTANCE: invention relates to polymer materials which are sensitive to UV radiation, which can be used to make UV induced structures in laser devices. Described is a single-step method of producing transparent block polymer material which is sensitive to UV radiation owing to presence of a uniformly distributed gold compound therein. The method involves preparation of an initial reaction mixture by dissolving a radical polymerisation initiator, selected from organic peroxides, and a noble metal compound, selected from salts with anions AuCl4 -, AuBr4 -, AuF4 -, Au(SCN)4 - and cations of quaternary ammonium bases, for example, N-cetylpyridinium, in an acrylic monomer at room temperature in liquid state. Synthesis of the polymer takes place via radical polymerisation in the mass of degassed reaction mixture while heating to temperature higher than 25°C, but lower than the boiling point of the monomer and then holding the mixture at the given temperature for 3-30 hours.
EFFECT: simplified method enables to obtain block materials which are sensitive to UV radiation.
5 cl, 2 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR LASER-INDUCED PRODUCTION OF CORE-SHELL NANOPARTICLES IN POLYMER MATRICES | 2022 |
|
RU2785991C1 |
GOLD-CONTAINING POLYMERISABLE ACRYLIC COMPOSITION, SPATIAL-MESH POLYMER MATERIAL FOR RECORDING INFORMATION AND PRODUCTION METHOD THEREOF | 2009 |
|
RU2429256C1 |
METHOD OF PRODUCING STABLE COLLOIDAL SOLUTION OF CADMIUM SULPHIDE NANOPARTICLES IN MEDIUM OF ACRYLIC MONOMERS | 2011 |
|
RU2466094C1 |
METHOD FOR PRODUCING COLLOIDAL SOLUTION OF AMPHIPHILIC BLOCK COPOLYMER OF BUTYLACRYLATE NARROWLY DISPERSED BY MOLECULAR WEIGHT AND ACRYLIC ACID WITH NARROW DISTRIBUTION OF MICELLES BY SIZE | 2016 |
|
RU2632004C1 |
LIQUID COMPOSITION FOR PHOTOPOLYMERISATION-ABLE FILM FOR HOLOGRAM RECORDING, METHOD OF COMPOSITION OBTAINING, METHOD OF OBTAINING SAID FILM | 2013 |
|
RU2541521C2 |
METHOD FOR OBTAINING POLYMER MATERIAL, CONTAINING INORGANIC NANO- OR MICROPARTICLES | 2014 |
|
RU2573508C1 |
SOLID-PHASE METHOD OF PRODUCING WATER-SOLUBLE BIOACTIVE NANOCOMPOSITE BASED ON MELANIN-MODIFIED HYALURONIC ACID SALT AND GOLD NANOPARTICLES | 2013 |
|
RU2532032C1 |
METHOD OF OBTAINING TRANSPARENT METAL-CONTAINING POLYMERISABLE COMPOSITIONS | 2014 |
|
RU2561278C1 |
METAL-IONOMER POLYMERS | 2016 |
|
RU2701874C2 |
LIQUID COMPOSITION OF PHOTOPOLYMERISATION-CAPABLE FILM FOR HOLOGRAM RECORDING, COMPOSITION OBTAINING METHOD | 2015 |
|
RU2574723C1 |
Authors
Dates
2011-04-10—Published
2009-10-05—Filed