FIELD: chemistry.
SUBSTANCE: catalyst contains noble metal nanoparticles on a mesoporous support. The noble metal in the catalyst is silver nanoparticles with average size of 2-5 nm, and the support is a mesoporous organometallic coordination polymer NH2-MIL-101(Al) with specific surface area greater than 2000 m2/g and mesopore volume of not less than 1.9 cm3/g, with the following ratio of components, wt %: Ag - 0.5-5, support - the balance.
EFFECT: catalyst is highly active and increases selectivity of the hydroamination process, cuts the duration of the hydroamination reaction and, as a result, increases efficiency of the process while maintaining high degree of conversion of acetylene hydrocarbons.
3 cl, 1 tbl, 5 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST FOR HYDROAMINATION OF ACETYLENE HYDROCARBONS AND METHOD FOR HYDROAMINATION OF ACETYLENE HYDROCARBONS USING SAID CATALYST | 2014 |
|
RU2544101C1 |
CATALYST FOR HYDROAMINATION OF ACETYLENE HYDROCARBONS AND METHOD OF HYDROAMINATION OF ACETYLENE HYDROCARBONS WITH THEREOF APPLICATION | 2013 |
|
RU2536043C1 |
METHOD OF CONVERSION OF ACETYLENE HYDROCARBONS | 2013 |
|
RU2536042C1 |
CATALYST FOR SELECTIVE REMOVAL OF ACETYLENE HYDROCARBON ADMIXTURES FROM ETHYLENE MONOMERS AND METHOD TO THIS END | 2012 |
|
RU2501606C1 |
METHOD OF PRODUCING POROUS COORDINATION POLYMER NH-MIL-101(Al) AND POROUS COORDINATION POLYMER NH-MIL-101(Al), OBTAINED USING SAID METHOD | 2015 |
|
RU2578599C1 |
BIMETALLIC CATALYST FOR LIQUID-PHASE SELECTIVE HYDROGENATION OF ACETYLENIC HYDROCARBONS AND METHOD FOR ITS PRODUCTION | 2022 |
|
RU2786218C1 |
METHOD FOR PRODUCING PALLADIUM-CONTAINING CATALYST FOR HYDROGENATION OF ACETYLENE COMPOUNDS | 2022 |
|
RU2814116C1 |
CATALYST FOR LIQUID-PHASE SELECTIVE HYDROGENATION OF ACETYLENE HYDROCARBONS AND A METHOD FOR PRODUCTION THEREOF | 2020 |
|
RU2738233C1 |
CATALYST FOR SELECTIVE HYDROGENATION OF ACETYLENE AND DIENE HYDROCARBONS IN C-C-HYDROCARBON FRACTIONS | 2014 |
|
RU2547258C1 |
CATALYST FOR ISOMERIZATION OF C-8 AROMATIC HYDROCARBONS | 2018 |
|
RU2676704C1 |
Authors
Dates
2015-10-27—Published
2014-11-26—Filed