FIELD: chemistry.
SUBSTANCE: invention relates to method for realisation of polymerisation process. (Co)polymerisation of monomer(s) is realised at first stage, with separation of product and monomers, oligomers, reaction products, as well as additives and solvents at second stage. Before and/or at second stage, i.e. at final stage, in reaction mixture added is substance, by means of which stripping and/or temperature impact is realised, which results in displacement of reaction equilibrium towards polymers, with slowing down of reaction rate with formation of monomer. Said substance represents alcohol or its derivatives, such as octanol, isopentanol, cyclohexanol, ethylene glycol, isoamyl alcohol.
EFFECT: elaboration of optimal two-step polymerisation method.
18 cl, 9 tbl, 2 dwg
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Authors
Dates
2016-02-20—Published
2011-05-12—Filed