FIELD: chemistry.
SUBSTANCE: invention relates to method for producing polysulphide of formula (I) HS-(CH2)n-O-(CH2)m-O-(CH2)p-[S-S-CH2)n-O-(CH2)m-O-(CH2)p]q-SH, where m is integer ranging from 1 to 4, n and r are integers in ranges of 1 to 10, q is integer in range of 1 to 60. Method for producing polysulphide consists in oxidation of simple bis-mercapto diether compound of formula (II) HS-(CH2)n-O-(CH2)m-O-(CH2)p-SH by elemental sulphur in presence of base and proton solvent.
EFFECT: invention increases selectivity of oxidation relative linear disulphides.
10 cl, 5 ex
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Authors
Dates
2016-04-20—Published
2012-04-10—Filed