FIELD: chemistry.
SUBSTANCE: invention discloses a method of producing liquid organic fuels from carbon dioxide, carbon monoxide and water, involving use of heteropolyacid 2-18 series, having chemical formula H6[P2W18O62], where degree of oxidation of tungsten is +6, which is exposed in presence of iron and zinc plates at minus 5 - plus 50 °C electromagnetic radiation in wavelength range of 3·105 to 10-2 nm and shorter to vary oxidation tungsten from +6 to +3 and +2, further, water solution of both heteropoly acids directly on synthetic organic liquid fuel, where in presence of chromium and nickel chips at +10 to +70 °C form a liquid organic fuel with simultaneous oxidation of anionic complexes of heteropoly acids to oxidised state, during formation of aqueous solution of heteropoly acid, having chemical formula H6[P2W18O62], after which obtained mixture is fed into a container for decantation, where there is separation of liquid fuel and water solution of heteropoly acid, which again can be used for synthesis.
EFFECT: technical result is to obtain a liquid organic fuels from carbon dioxide, carbon monoxide and water at lower temperatures using a variety of external sources of energy in form of electromagnetic radiation.
1 cl, 1 dwg, 1 ex
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Authors
Dates
2016-04-20—Published
2015-05-25—Filed