CATALYST FOR SYNTHESIS OF HYDROCARBONS FROM CO AND H AND PREPARATION METHOD THEREOF Russian patent published in 2016 - IPC B01J23/75 B01J21/04 B01J21/08 B01J37/02 B01J37/08 B01J37/18 C07C1/04 C07C9/00 

Abstract RU 2586069 C1

FIELD: chemistry.

SUBSTANCE: invention relates to chemical industry, including petroleum and gas chemistry, and can be applied during preparation of catalysts for producing hydrocarbons from CO and H2 via Fischer-Tropsch synthesis. Catalyst contains in wt.%: cobalt 16.1-19.0, aluminium additives 0.8-1.0, silica gel carrier - the rest. Obtaining catalyst includes drying carrier at 140-160 °C for 2-4 hours, wetting carrier with aqueous cobalt nitrate solution of concentration 35-55 wt.% with adding aluminium nitrate in weight ratio Co:Al2O3 100:5 in impregnation solution. Then catalyst is dried in two stages at 80-100 °C and at 100-150 °C for 2-4 hours and fired at 250-300 °C for 4-6 hours. Catalyst activation is performed with hydrogen at 380-400 °C for 0.75-1 h.

EFFECT: technical result is obtaining cobalt-aluminium-silicate catalyst with high catalytic activity and selectivity relative to C5+ hydrocarbons formation and reduced selectivity relative to methane formation.

2 cl, 1 dwg, 6 ex

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RU 2 586 069 C1

Authors

Savostyanov Aleksandr Petrovich

Bakun Vera Grigorevna

Yakovenko Roman Evgenevich

Narochnyj Grigorij Borisovich

Dates

2016-06-10Published

2015-06-15Filed