FIELD: chemistry.
SUBSTANCE: invention relates to chemical industry, including petrochemistry, gas chemistry, coal chemistry and can be used in preparing catalysts for the process of producing synthetic hydrocarbons from CO and H2 by Fischer-Tropsch method. Invention relates to a cobalt catalyst which is selective with respect to formation of hydrocarbons of diesel fraction C11-C18, enriched with isoparaffins, and a method of preparing a catalyst which includes preparation and heat treatment of a cobalt catalyst by impregnation and zeolite ZSM-5 by ion exchange, mixing powders of cobalt catalyst, ZSM-5 zeolite and boehmite binder, obtaining a homogeneous mass, molding granules, thermal treatment, milling and activation of the catalyst. Catalyst contains the following components, wt%: cobalt catalyst with an aluminum additive on a silica gel support – 30–40; binding boehmite – 30–40; zeolite ZSM-5 as a balance; wherein the cobalt catalyst with aluminum on the silica gel support contains the following, wt%: cobalt – 6.5–8.7; aluminum additive – 0.33–0.43; silica gel carrier as a balance; wherein zeolite ZSM-5 contains, wt%: palladium additive – 0.08–0.12; zeolite ZSM-5 in ammonium form as a balance.
EFFECT: catalyst obtained using said method has improved catalytic properties.
2 cl, 9 dwg, 7 ex
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Authors
Dates
2019-08-29—Published
2018-10-17—Filed