FIELD: chemistry.
SUBSTANCE: invention relates to a method of producing α-methylsubstituted carbonyl compounds of gthe eneral formula R1-CO-CR3(CH3)-R2, where: R1 and R2-hydrogen H or a linear or branched alkyl radical containing 1 to 12 carbon atoms, R3-H or CH3 radical, which are feedstock for producing a number of chemical products and drugs, are used as solvents and can be used as a base for producing high-octane motor fuel components. Method involves conversion of initial gas-vapour mixture of carbonyl compound selected from compounds of general formula R4-CO-CHR5-R6, where: R4 and R6-H or a linear or branched alkyl radical containing 1 to 9 carbon atoms, R5-H or CH3 radical, and methanol using copper-containing catalyst when introducing in initial reaction mix of hydrogen.
EFFECT: proposed method allows to increase the catalyst interregeneration runtime in several times, and consequently, the amount of product obtained per unit volume of the reactor.
3 cl, 1 tbl, 6 ex
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Authors
Dates
2016-08-20—Published
2015-06-25—Filed