METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE Russian patent published in 2013 - IPC C07C217/84 C07C213/08 C07C209/36 C07C211/48 

Abstract RU 2472774 C1

FIELD: chemistry.

SUBSTANCE: method of producing N-methyl-para-anisidine involves N-alkylation of para-anisidine and/or para-nitroanisole with methanol in vapour phase on a dehydrogenating copper-chromium catalyst at temperature of 180-260°C and atmospheric pressure, followed by separation of products by rectification. The invention also relates to a method of producing N-methyl-para-anisidine by N-alkylation of para-nitroanisole and/or para-anisidine with methanol in vapour phase at temperature of 180-260°C and atmospheric pressure, followed by separation of products by rectification on a dehydrogenating catalyst of the following composition: CuO - 25%; ZnO - 25%; CaO - 5%; Al2O3 - the balance or CuO - 35-45%; ZnO - 25-35%; NiO - 3-8%; Al2O3 - the balance.

EFFECT: obtaining N-methyl-para-anisidine with high purity and high output, which enables highly profitable, large-tonnage production.

18 cl, 8 ex

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RU 2 472 774 C1

Authors

Frolov Aleksandr Jur'Evich

Ivanov Jurij Aleksandrovich

Beljakov Nikolaj Grigor'Evich

Dates

2013-01-20Published

2011-09-28Filed