FIELD: chemistry.
SUBSTANCE: method of producing N-methyl-para-anisidine involves N-alkylation of para-anisidine and/or para-nitroanisole with methanol in vapour phase on a dehydrogenating copper-chromium catalyst at temperature of 180-260°C and atmospheric pressure, followed by separation of products by rectification. The invention also relates to a method of producing N-methyl-para-anisidine by N-alkylation of para-nitroanisole and/or para-anisidine with methanol in vapour phase at temperature of 180-260°C and atmospheric pressure, followed by separation of products by rectification on a dehydrogenating catalyst of the following composition: CuO - 25%; ZnO - 25%; CaO - 5%; Al2O3 - the balance or CuO - 35-45%; ZnO - 25-35%; NiO - 3-8%; Al2O3 - the balance.
EFFECT: obtaining N-methyl-para-anisidine with high purity and high output, which enables highly profitable, large-tonnage production.
18 cl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-PHENETIDINE | 2011 |
|
RU2471771C1 |
METHOD FOR SELECTIVE PRODUCTION OF N-METHYL-PARA-ANISIDINE | 2012 |
|
RU2508288C1 |
METHOD OF SYNTHESIS OF N-ALKYLANILINES | 1998 |
|
RU2152382C1 |
N-METHYLALANINE PRODUCTION PROCESS | 2003 |
|
RU2240308C1 |
CATALYST AND METHOD OF OBTAINING N-METHYLANILINE | 2007 |
|
RU2346740C1 |
ANTIDETONATING ADDITIVE ON THE BASIS OF MIXTURE OF METHYLATED TOLUIDINES AND METHOD OF SELECTIVE RECEIVING OF MIXTURE OF N-METHYL-TOLUIDINES | 2015 |
|
RU2659221C2 |
COPPER-CHROMIUM-ZINC CATALYST FOR HETEROGENEOUS REACTIONS | 2014 |
|
RU2555842C1 |
METHOD FOR PRODUCING N-METHYL-PARA-ANISIDINE | 2016 |
|
RU2631510C1 |
METHOD FOR PRODUCTION OF N-METHYL ANILINE | 1995 |
|
RU2066679C1 |
METHOD FOR PREPARING N-METHYLANILINE | 2004 |
|
RU2270187C2 |
Authors
Dates
2013-01-20—Published
2011-09-28—Filed