FIELD: chemistry.
SUBSTANCE: invention relates to organic chemistry, specifically to a method of producing functionally substituted aziridinofullerenes, which can be used as complexing agents, sorbents, biologically active compounds, as well as for creation of new materials with given properties. Method comprises reaction of fullerene C60 with framework polycyclic azides RN3 (where R = 1-adamantyl, norbornan-1-yl, cholestan-3-yl) in presence of copper Cu(OTf)2, taken in molar ratio C60:RN3:Cu(OTf)2=1:(1-5):(0.5-2), in a chlorobenzene solution at 100 °C for 1-5 hours.
EFFECT: output of obtained products is 30-50 %.
1 cl, 1 tbl, 1 ex
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Authors
Dates
2016-09-10—Published
2014-12-10—Filed