FIELD: chemistry.
SUBSTANCE: invention relates to organic chemistry, specifically to a method of producing 1-azido-2-butyl-1,2-dihydro(C60-Ih)[5,6]fullerene of formula (1) 
, which can be used as a complexing agent, sorbent and biologically active compound, as well as in production of novel materials with given properties. The method includes reacting fullerene C60 with tributyltin azide (n-Bu3SnN3) in the presence of a stoichiometric amount of Cu(OTf)2. The molar ratio C60:n-Bu3SnN3:Cu(OTf)2 is equal to 1:(1-5):(0.5-2). The reaction is carried out in a solution of dry chlorobenzene at 100°C in an argon atmosphere. The disclosed method enables to obtain 1-azido-2-butyl-1,2-dihydro(C60-Ih)[5,6]fullerene (1) with output of up to 30%.
EFFECT: improved method.
1 tbl, 5 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF PRODUCING 1-BROMO-2-AZIDO-1,2-DIHYDRO(C-I)[5,6]FULLERENE | 2013 |
|
RU2551279C2 |
| METHOD OF PRODUCING AZIRIDINO[2',3':1,9]FULLERENES[60], CONTAINING FRAMEWORK AND POLYCYCLIC SUBSTITUTES | 2014 |
|
RU2596876C2 |
| METHOD FOR OBTAINING N-CYCLOALKYLAZIRIDINO[2',3':1,9]FULLERENES[60] | 2014 |
|
RU2574071C1 |
| METHOD FOR PRODUCING N-ARYLAZIRIDINUM[2 ', 3 ': 1.9]FULLERENE [60] | 2014 |
|
RU2594562C2 |
| METHOD OF PRODUCING N-ALKIL AZIRIDINO[2',3':1,9] FULLERENE [60] | 2014 |
|
RU2594561C2 |
| METHOD OF PRODUCING 1-IODO-2-AZIDO(C-I)[5,6]FULLERENE | 2011 |
|
RU2484010C2 |
| METHOD OF PRODUCING N-ALKYL AND N-ARYLCARBOXAMIDYL-1aH,2'H-[1,2]PYRAZOLINO[3',4':1,9](C-I)-[5,6]FULLERENES | 2012 |
|
RU2517170C2 |
| METHOD OF OBTAINING 1-AZIDO-2-ETHYL-1,2-DIHYDRO(C-I)[5,6]FULLERENE | 2013 |
|
RU2540087C2 |
| METHOD FOR PRODUCING 1'-[N-(ARYLMETHYL)AMINO]-(C60-IH)[5,6]FULLERO [2',3':1,9] CYCLOPROPANES | 2016 |
|
RU2629756C1 |
| METHOD OF PRODUCING 3'-METHYL-3'-FURYL- OR 3'-METHYL-3'-THIENYL-3'H-CYCLOPROPA[1,9](C-I)[5,6]FULLERENES | 2011 |
|
RU2478629C2 |
