Show metadata Hide metadata

(19)

(11)

2 594 562

(13)

(51)

IPC

C07D203/26(2006-01-01)

(21) (22)

Application

2014150376/04, 2014-12-11

(24)

Start date

2014-12-11

(22)

Actual filing date

2014-12-11

(45)

Published

2016-08-20

(72)

Inventor

Dzhemilev Usein MemetovichTuktarov Ajrat RamilevichAkhmetov Arslan RifkhatovichRyabinina Tatyana Egorovna

(73)

Holder

Federalnoe Gosudarstvennoe Byudzhetnoe Uchrezhdenie Nauki Institut Neftekhimii I Kataliza Rossijskoj Akademii Nauk

METHOD FOR PRODUCING N-ARYLAZIRIDINUM[2 ', 3 ': 1.9]FULLERENE [60] Russian patent published in 2016 - IPC C07D203/26

Abstract RU 2594562 C2

FIELD: chemistry.

SUBSTANCE: present invention relates to organic chemistry, namely to a method for producing N-arylaziridinumfullerene, which can be used as complexing agents, sorbents, biologically active compounds, as well as for creating new materials with given properties. Method involves reaction of fullerene C₆₀ with arylaziridinums RN₃ (where R = Ph, 4-Cl-Ph 2-NO₂-Ph 2-MeO-Ph, Naph) in the presence of lanthanum La (OTf)₃, taken in the molar ratio C₆₀: RN₃: La (OTf)₃= 1: (0.5-2):(0.5-2), at the temperature of 80 °C, in chlorobenzene for 1-3 hours.

EFFECT: obtaining N-arylaziridinum [2′,3′: 1,9]fullerene [60] (1) with the output of 20-50 %.

1 cl, 1 tbl, 1 ex

Similar patents RU2594562C2

Title	Year	Author	Number
METHOD OF PRODUCING AZIRIDINO[2',3':1,9]FULLERENES[60], CONTAINING FRAMEWORK AND POLYCYCLIC SUBSTITUTES	2014	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich Khuzin Artur Albertovich	RU2596876C2
METHOD FOR OBTAINING N-CYCLOALKYLAZIRIDINO[2',3':1,9]FULLERENES[60]	2014	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich Muslimov Zabir Sabirovich	RU2574071C1
METHOD OF PRODUCING N-ALKIL AZIRIDINO[2',3':1,9] FULLERENE [60]	2014	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich Tuktarova Regina Adikovna	RU2594561C2
METHOD OF PRODUCING 1-BROMO-2-AZIDO-1,2-DIHYDRO(C-I)[5,6]FULLERENE	2013	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich Jarullin Il'Dar Rafisovich	RU2551279C2
METHOD OF PRODUCING 1-AZIDO-2-BUTYL-1,2-DIHYDRO(C-I)[5,6]FULLERENE	2013	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Akhmetov Arslan Rifkhatovich Jarullin Il'Dar Rafisovich	RU2551286C1
METHOD FOR PRODUCING 1'-[N-(ARYLMETHYL)AMINO]-(C60-IH)[5,6]FULLERO [2',3':1,9] CYCLOPROPANES	2016	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Shakirova Zulfiya Rasimovna	RU2629756C1
METHOD OF OBTAINING 6-ALKYL(ARYL)-2,3-(C-I)[5,6]FULLERO-2,3,4,5-TETRAHYDROPYRIDINES	2014	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Khuzin Artur Al'Bertovich Shakirova Zul'Fija Rasimovna	RU2565782C1
1,9-(2'-HYDROXYMETHYL-1',4'-DIOXANO)-1,9-DIHYDRO-(C-I)[5,6]FULLERENE AND ITS PRODUCTION METHOD	2021	Kinzyabaeva Zemfira Sabitovna	RU2785546C2
METHOD OF SELECTIVE OBTAINING OF 1'-ALKYL-1'-N-CYCLOHEXYLCARBOXAAMIDYLCYCLOPROPA[2',3':1,9](C-I)[5,6]FULLERENES	2013	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Khuzina Lilija Linatovna	RU2540080C2
METHOD OF PRODUCING N-ALKYL AND N-ARYLCARBOXAMIDYL-1aH,2'H-[1,2]PYRAZOLINO[3',4':1,9](C-I)-[5,6]FULLERENES	2012	Dzhemilev Usein Memetovich Tuktarov Ajrat Ramilevich Khuzina Lilija Linatovna	RU2517170C2

RU 2 594 562 C2

Authors

Dzhemilev Usein Memetovich

Tuktarov Ajrat Ramilevich

Akhmetov Arslan Rifkhatovich

Ryabinina Tatyana Egorovna

Dates

2016-08-20—Published

2014-12-11—Filed