FIELD: chemistry.
SUBSTANCE: invention relates to method of obtaining aziridino[2',3':1,2]fullerene[60] of general formula (1): by interaction of fullerene C60 with hydrazoic acid (HN2), generated in situ by reaction of NaN3 with H2SO4, taken in mole ratio C60:NaN3 : H2SO4=1 : (100-120):(100-120), in chlorobenzene at temperature 60°C for 2-4 hours. Target product is obtained with 24-35% output in one stage.
EFFECT: increase of output of suitable.
1 dwg, 1 tbl
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Authors
Dates
2012-11-20—Published
2010-12-07—Filed