FIELD: chemistry.
SUBSTANCE: invention relates to chemical engineering, specifically to a method of purifying industrial sewage water from hypochlorite ions, formed during chlorination of lithium, sodium and calcium hydroxides. Method for catalytic decomposition of hypochlorite ions involves contacting a solution containing hypochlorite ions with a nickel-containing catalyst in form of particles at temperature of 32-67 °C, with extraction of gaseous oxygen. Nickel-containing catalyst used is basic nickel carbonate, dispersed on a nanoporous composite carbon material, containing as binder a fluoroplastic suspension at ratio of components, wt%: nanoporous composite carbon material 49-54, fluoroplastic suspension 5-9, basic nickel carbonate - balance.
EFFECT: efficient purification from hypochlorite ions with high rate of decomposition and at lower temperatures.
1 cl, 1 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF CATALYTIC DECOMPOSITION OF HYPOCHLORITE | 2001 |
|
RU2203850C2 |
METHOD FOR CATALYTIC DECOMPOSITION OF HYPOCHLORITE | 1992 |
|
RU2091296C1 |
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METHOD OF LITHIUM CHLORIDE PRODUCING | 1996 |
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METHOD OF PRODUCTION OF LITHIUM CHLORIDE | 2005 |
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RU2808979C1 |
METHOD FOR PRODUCING CHLORINE AND ALKALI | 0 |
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SU1030424A1 |
LAYERED HYDROXIDE WITH HYDROTALCITE STRUCTURE CONTAINING NICKEL WITH OXIDATION RATE +3, AND METHOD FOR PREPARING IT | 2013 |
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RU2540402C1 |
Authors
Dates
2016-11-10—Published
2015-06-16—Filed