METHOD FOR REDUCTION OF BRANCHED KETONES Russian patent published in 2016 - IPC C07C1/22 C07C1/24 C07C9/16 

Abstract RU 2605427 C1

FIELD: chemistry.

SUBSTANCE: invention relates to reduction of branched ketones to saturated hydrocarbons by catalytic hydrogenation of ketone. Method is characterized by that, catalyst used is a composite, consisting of a mechanical mixture of a hydrogenation catalyst from among metals: Pt, Pd, Ru, Au, Ni, Cu on a support - aluminium oxide and/or silicon oxide and dehydration catalyst, in form of cation-exchange resin in H-form, and/or deposited on a solid support phosphoric and/or sulphuric acid, and/or zeolite catalyst with a structure selected from: MFI, MEL, BEA, MTT, TON.

EFFECT: use of disclosed method allows to increase activity, selectivity and stability of catalysts for hydrogenation of branched ketones to corresponding alkanes or mixtures thereof with alcohols.

3 cl, 1 tbl, 15 ex

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RU 2 605 427 C1

Authors

Egizarjan Arkadij Mamikonovich

Golovachev Valerij Aleksandrovich

Ivanov Dmitrij Petrovich

Klejmenov Andrej Vladimirovich

Kondrashev Dmitrij Olegovich

Miroshkina Valentina Dmitrievna

Noskov Aleksandr Stepanovich

Pirjutko Larisa Vladimirovna

Kharitonov Aleksandr Sergeevich

Dates

2016-12-20Published

2015-10-20Filed