FIELD: chemistry.
SUBSTANCE: invention relates to novel compounds in a series of spiro[benzopyran-indolines]. Described is a 6-(1,3-benzimidazo-2-yl)-7-hydroxy-substituted spiro[benzopyran-indoline] of general formula 1, where R1 is C1-C6 alkyl, R2 is H, halogen.
EFFECT: obtaining a novel compound containing a spirocyclic fragment, having intense fluorescence with abnormally high Stokes shift and developing photochromic properties.
1 cl, 1 tbl, 2 ex
Title | Year | Author | Number |
---|---|---|---|
PHOTOCHROMIC DERIVATIVES OF 5'-HYDROXYMETHYL-6-NITRO-1',3',3'-TRIMETHYLSPIRO[2N-1-BENZOPYRAN-2,2'-INDOLINE] | 2019 |
|
RU2694904C1 |
PHOTOCHROMIC 5'-VINYL-6-NITRO-SPIROBENZOPYRAN DERIVATIVES AND PRODUCTION METHOD THEREOF | 2011 |
|
RU2458927C1 |
5-FORMYL-SUBSTITUTED INDOLINE SPIROBENZOPYRANS AND METHOD OF PRODUCING THEM | 2008 |
|
RU2358977C1 |
PERCHLORATES 1,3,3-TRIMETHILSPIRO[CHROMENE-2,2'-INDOLINE] WITH PHOTOCHROMIC PROPERTIES | 2016 |
|
RU2627358C1 |
1,3,3-TRIMETHYL-5-METHOXY-6´-BROMO-8´-[(Е)-2-(1´´,3´´,3´´-TRIMETHYL-5-METHOXY-3H-INDOLIUM- 2´´-YL)VINYL]-SPIRO[INDOLINE-2,2´-2H-CHROMENE] IODIDE | 2022 |
|
RU2786996C1 |
METHOD OF PRODUCING SPIROPYRANS OF BENZTHIAZOL SERIES | 0 |
|
SU1608189A1 |
5'-(1,3-BENZOTHIAZOL-2-YL)-SUBSTITUTED SPIRO[INDOLINE-NAPHTHOPYRANS] AND USE THEREOF AS PHOTOREVERSIBLE COMPLEXING AGENTS | 2011 |
|
RU2458926C1 |
METHOD FOR PREPARING DERIVATIVE OF INDOLINOSPIROPYRANE | 2001 |
|
RU2293738C2 |
1-SUBSTITUTED-3-[(1E)-1-ALKENYL]-4-(5-ALKOXY-1,2-DIMETHYL-1H-INDOL-3-YL)-1H-PYRROLE-2,5-DIONES AND USE THEREOF AS FLUORESCENT PHOTOCHROMES | 2008 |
|
RU2397979C2 |
4-SUBSTITUTED-3-(1-ALKYL-2-CHLORO-1H-INDOL-3-YL)FURAN-2,5-DIONES, SYNTHESIS METHOD THEREOF AND USE IN PHOTOCHEMICAL GENERATION OF STABLE FLUORESCENT COMPOUNDS AND 4,5-SUBSTITUTED-6-ALKYL-1H-FURO[3,4-c]CARBAZOLE-1,3(6H)-DIONES, SYNTHESIS METHOD THEREOF AND USE AS FLUOROPHORES | 2009 |
|
RU2396267C1 |
Authors
Dates
2017-01-10—Published
2015-11-16—Filed