FIELD: chemistry.
SUBSTANCE: invention relates to a method of supercritical fluid extraction of uranium complexes. Method involves creation of supercritical solvent in a reactor and dissolving uranium complexes with ligands in presence of water, extracting dissolved uranium complexes with ligands from reactor. In medium of supercritical solvent when stored in supercritical state temperature gradient is created in range of 0.10–0.23 °C/cm along its vertical column at a higher temperature of lower level of column as compared to its upper level, extraction of metal complexes with ligands from reactor is carried out from a layer, on height of 1/3 to 2/5 of column of supercritical solvent from its lower level.
EFFECT: invention enables to change isotopic composition of metal during extraction thereof from reactor.
3 cl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
METAL SEPARATION METHOD | 2006 |
|
RU2322714C1 |
METHOD FOR SUPERCRITICAL FLUIDIC EXTRACTION OF METALS | 1999 |
|
RU2168779C2 |
SEPARATIONS PERFORMED WITH RESPECT TO TARGET DEVICE | 2015 |
|
RU2708226C2 |
EXTRACTION MIXTURE FOR SUPERCRITICAL EXTRACTION OF ACTINIDE OXIDES | 2005 |
|
RU2295788C1 |
METHOD OF REMOVING CHLORIDES OF ALKALI METALS, URANIUM AND PLUTONIUM CHLORIDES FROM THE SURFACE OF SOLID BODIES | 2021 |
|
RU2770418C1 |
COMPOSITION FOR CONVERSION OF SOLID FORMS OF ACTINOIDS AND RARE EARTH ELEMENTS INTO A SOLUBLE FORM | 2020 |
|
RU2755814C1 |
METAL EXTRACTION PROCESS | 2003 |
|
RU2274486C2 |
METHOD OF DECONTAMINATING MATERIALS | 2012 |
|
RU2501106C1 |
EXTRACT ENCAPSULATION INTO POROUS PARTICLES | 2012 |
|
RU2549780C1 |
METHOD OF GETEROGENEOUS CHEMICAL ENGINEERING PROCESSES PERFORMING IN ADIABATIC TUBE REACTOR AT SUPERCRITICAL PRESSURE | 2006 |
|
RU2355469C2 |
Authors
Dates
2017-01-10—Published
2015-05-29—Filed