FIELD: electrical engineering.
SUBSTANCE: invention relates to electrical engineering and can be used in production of lithium-ion accumulators (LIA) and storage batteries on their basis intended for use as power accumulators for electric vehicles, alternative power engineering, uninterrupted power supply sources, power recovery systems and levelling network loads. In design of the proposed lithium-ion accumulator combined are: an active material of the negative electrode on the base Li4Ti5O12 and an active material of the positive electrode on Li3V2(PO4)3. Active material of the negative electrode on the base Li4Ti5O12 can be chromium-deposited on titanium positions and is a compound of the following composition Li4Ti5-xCrxO12, where 0<x≤0.2. Active material of the positive electrode can be sodium-deposited on lithium positions, with one or more metals from a group comprising magnesium, aluminium, yttrium and lanthanum on vanadium positions, fluorine or chlorine on phosphate positions, and is a compound of the following composition Li3-xNaxV2-yMy(PO4)3-zHalz/C, where M is one or more metals from a group comprising Mg, Al, Y, La; G=F, Cl; 0<x≤0.1; 0<y≤0.2; 0<z≤0.16. Crystals of active materials of the negative and the positive electrodes can be coated with a surface layer of carbon, which is obtained due to introduction of into a mixture of initial reagents of a carbon-containing precursor – starch.
EFFECT: invention allows to create a design of high-capacity LIA with higher power safety and stability during cycling.
5 cl, 4 dwg
Title | Year | Author | Number |
---|---|---|---|
CATHODE MATERIAL FOR LITHIUM ION BATTERIES BASED ON MODIFIED PHOSPHATES | 2013 |
|
RU2556011C2 |
METHOD FOR PRODUCING COMPOSITE ANODE MATERIAL TiNbO/C FOR LITHIUM-ION BATTERIES | 2022 |
|
RU2799067C1 |
NANO-DIMENSION COMPOSITE MATERIAL CONTAINING MODIFIED NANO-DIMENSION LITHIUM-IRON PHOSPHATE AND CARBON | 2009 |
|
RU2402114C1 |
COMPOSITE CATHODIC MATERIAL OF LITHIUM ION BATTERY BASED ON LIV(PO)WITH NASIKON STRUCTURE AND METHOD OF ITS OBTAINING | 2013 |
|
RU2542721C1 |
ANODE MATERIAL FOR LITHIUM- AND SODIUM-ION ACCUMULATORS AND A METHOD FOR PRODUCTION THEREOF | 2020 |
|
RU2730001C1 |
ANODE MATERIAL FOR LITHIUM ELECTROLYTIC CELL AND METHOD OF PREPARING SAID MATERIAL | 2009 |
|
RU2397576C1 |
LiCrTiO-BASED MATERIAL OF ANODE IN LITHIUM-ION BATTERY BASED ON SPINEL-STRUCTURE AND METHOD OF ITS PRODUCTION | 2014 |
|
RU2558140C1 |
COMPOSITE CATHODE MATERIAL FOR LITHIUM-ION BATTERIES | 2014 |
|
RU2584678C1 |
ELECTRODE MASS, ELECTRODE COMPOSITE MATERIAL, METHOD OF ITS PRODUCTION AND ITS USE IN METAL-ION ACCUMULATORS | 2020 |
|
RU2732368C1 |
METHOD FOR PROCESSING MATERIALS OF METAL-ION BATTERIES BASED ON VANADIUM AND TITANIUM COMPOUNDS | 2022 |
|
RU2792869C1 |
Authors
Dates
2017-01-23—Published
2015-05-05—Filed