FIELD: metallurgy.
SUBSTANCE: invention relates to hydrometallurgy of uranium and can be used in regeneration as a result of chemical treatment, defective or unclaimed fuel elements. Oxidised fragments are treated with (3-6)N nitric acid in ratio of reacting phases S:L = 1:(3÷6) for 4–6 hours at temperature 70–90 °C. Method then includes filtration and extraction of uranium from solution. Invention allows to significantly reduce rate of corrosion of equipment due to selective dissolution of uranium, provides more than 98 % extraction of uranium without using hydrofluoric acid and also significantly optimises processing.
EFFECT: method of processing uranium-zirconium wastes in form of fuel elements consists in that initial fuel elements are subjected to fragmentation and oxidised in air at 1,000–1,250 °C to constant weight.
4 cl, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PROCESSING NUCLEAR WASTES | 2008 |
|
RU2379774C1 |
METHOD OF PROCESSING URANIUM-ZIRCON WASTES | 2008 |
|
RU2379776C1 |
METHOD FOR NUCLEAR PRODUCTION WASTE PROCESSING | 2017 |
|
RU2646535C1 |
METHOD OF PROCESSING URANIUM-CONTAINING COMPOSITIONS | 2008 |
|
RU2379775C1 |
METHOD FOR OPENING URANIUM-ZIRCONIUM FUEL COMPOSITION | 2022 |
|
RU2797998C1 |
METHOD OF OXIDATING TREATMENT (VOLOXIDIATION) OF IRRADIATED NUCLEAR FUEL | 2017 |
|
RU2654536C1 |
METHOD OF PROCESSING ACID-RESISTANT URANIUM-CONTAINING MATERIALS | 2020 |
|
RU2743383C1 |
METHOD FOR RECOVERING URANIUM-GADOLINIUM SCRAP | 2002 |
|
RU2237299C2 |
PROCEDURE FOR PROCESSING SILICON CONTAINING WASTES OF URANIUM PRODUCTION | 2014 |
|
RU2576819C1 |
METHOD OF RECEIVING OF URANIUM OXIDE AT PROCESSING OF URANIC FUEL ELEMENTS | 2007 |
|
RU2363998C2 |
Authors
Dates
2017-03-16—Published
2016-04-11—Filed