FIELD: chemistry.
SUBSTANCE: invention relates to a method for producing low-sulphur, low pour-point diesel fuel. Hydrotreated diesel fraction with a sulphur content of 0.001 wt % or less, is mixed with hydrogen and directed to a reactor with the top bed of isodewaxing zeolite-based catalyst and the bottom bed of hydrofinishing catalyst. The hydrofinishing catalyst contains as follows, wt %: 6.0-18.0 of nickel (with reference to NiO), 6.0-18.0 of molybdenum (with reference to MoO3) or 6.0-18.0 of tungsten (with reference to WO3) and 0-0.20 of silicone oxide, aluminium oxide - the rest. The volume ratio of isodewaxing catalyst to hydrofinishing catalyst is between 5:1 and 20:1. Isodewaxing and hydrofinishing processes are carried out at a temperature of 300-380°C, pressure of 4.0-5.5 mPa, raw material volumetric flow rate (in relation to the isodewaxing catalyst volume) of 2.0-6.0 h-1, and hydrogen/raw material ratio of 350:1-700:1 nl/l. Hydrogen-bearing gas is separated, the product of joint isodewaxing/hydrofinishing process is stabilised followed by separation of light hydrocarbons and producing the target product.
EFFECT: improved method for producing low-sulphur, low pour-point diesel fuel, resulting in high yield of the target product, containing 8 wt % or less of polycyclic aromatic hydrocarbons.
4 cl, 3 tbl, 10 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST FOR HIGH-TEMPERATURE HYDROFINISHING OF HYDROTREATED WAXY DIESEL FRACTIONS FOR OBTAINING DIESEL FUELS FOR COLD AND ARCTIC CLIMATE AND PREPARATION METHOD THEREOF | 2015 |
|
RU2583788C1 |
CATALYST FOR HYDROISODEWAXING OF DIESEL FRACTIONS FOR OBTAINING LOW-SOLIDIFICATION DIESEL FUEL AND METHOD OF PRODUCING LOW-SOLIDIFICATION DIESEL FUEL USING SAME | 2023 |
|
RU2826904C1 |
METHOD OF OBTAINING BASES OF WAXY ARCTIC OILS | 2015 |
|
RU2570649C1 |
METHOD FOR PRODUCTION OF BASE OF LOW-SOLIDIFYING ARCTIC OILS | 2021 |
|
RU2785762C2 |
CATALYST FOR COMBINED OBTAINING OF WAXY FUELS AND ISOPARAFFIN OILS AND METHOD FOR COMBINED OBTAINING OF WAXY FUELS AND ISOPARAFFIN OILS IN PROCESS OF ISOMERISATION/CRACKING OF HIGH-PARAFFIN RAW MATERIAL WITH APPLICATION THEREOF | 2014 |
|
RU2575172C1 |
METHOD OF OBTAINING MULTIGRADE STANDARDIZED DIESEL FUEL | 2018 |
|
RU2673558C1 |
METHOD FOR OBTAINING DIESEL FUEL FROM SOLID SYNTHETIC HYDROCARBONS OBTAINED AS PER FISCHER-TROPSCH METHOD, AND CATALYSER FOR ITS OBTAINING | 2011 |
|
RU2493237C2 |
METHOD FOR PRODUCING WINTER AND ARCTIC DIESEL FUELS FROM STRAIGHT-RUN DIESEL FRACTIONS WITH A SULFUR CONTENT OF UP TO 5000 MG/KG AND NITROGEN UP TO 200 MG/KG | 2021 |
|
RU2758847C1 |
METHOD OF PRODUCING SWEETENED DIESEL FUEL WITH SUPER LOW CONTENTS OF SULPHUR | 2008 |
|
RU2362797C1 |
METHOD OF OBTAINING LOW-VISCOUS WHITE OILS | 2014 |
|
RU2549898C1 |
Authors
Dates
2017-04-12—Published
2016-03-10—Filed