FIELD: chemistry.
SUBSTANCE: described preliminary prepolymerized component for the polymerization of olefins. Mentioned catalyst component comprises a non-stereospecific solid catalyst component, which comprises Ti, Mg and halogen, as well as some amount of the (co) polymer of alpha-olefin CH2= CHR1, where R1 represents a hydrocarbon group of C1-C12 in the range from 0.1 to 500 g per gram of mentioned solid catalyst component. Mentioned (co) polymer has isotacticity, expressed in terms of isotactic pentads, amounting to more than 60 molar %, and the intrinsic viscosity measured in tetralin at 135°C with the volume of at least 1.0 dl/g. The catalyst system for olefin polymerization is also described, as well as the method of (co) polymerization of ethylene and method for preparation of preliminary polymerized catalyst component.
EFFECT: use of the prepolymerized catalyst in the polymerization of ethylene with high yield of product and regular morphology.
14 cl, 7 tbl, 4 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST COMPONENTS FOR POLYMERISATION OF OLEFINS AND CATALYSTS MADE THEREFROM | 2013 |
|
RU2634425C2 |
CATALYST COMPONENTS FOR POLYMERISATION OF OLEFINS | 2014 |
|
RU2613069C1 |
COMPONENT OF PREPOLYMERIC CATALYST, METHOD FOR ITS PREPARING, CATALYST FOR POLYMERIZATION OF OLEFINS AND METHOD FOR POLYMERIZATION OF OLEFINS USING THEREOF | 1999 |
|
RU2234516C2 |
CATALYST COMPONENTS FOR POLYMERISATION OF OLEFINS | 2009 |
|
RU2493175C2 |
COMPONENTS OF CATALYST FOR POLYMERIZATION OF OLEFINS, CATALYST, METHOD FOR PREPARING PROPYLENE POLYMERS AND PROPYLENE POLYMER | 2001 |
|
RU2279442C2 |
BEAD COMPONENT OF OLEFIN POLYMERIZATION CATALYST, PROCESS FOR PREPARATION THEREOF, OLEFIN POLYMERIZATION CATALYST, AND PROCESS FOR POLYMERIZATION OF OLEFINS | 1993 |
|
RU2126420C1 |
CATALYST COMPONENTS FOR POLYMERISATION OF OLEFINS | 2012 |
|
RU2598073C2 |
CATALYST COMPONENTS AND CATALYSTS FOR OLEFIN POLYMERIZATION OBTAINED FROM THEM | 2017 |
|
RU2747650C2 |
METHOD FOR ETHYLENE POLYMERIZATION | 2015 |
|
RU2660910C1 |
CATALYST COMPONENTS FOR POLYMERISATION OF OLEFINS | 2015 |
|
RU2649386C2 |
Authors
Dates
2017-05-12—Published
2014-06-10—Filed