FIELD: chemistry.
SUBSTANCE: invention relates to a method for producing saturated aldehydes by contacting a liquid organic feed containing unsaturated aldehydes with hydrogen or hydrogen-containing gas in presence of crustal catalyst comprising palladium particles of not more than 6 nm in size, applied in form of a layer not thicker than 150 microns on exterior surface of porous alumina carrier granules. Herewith the carrier has not less than 60% of pores with a diameter of 5 to 50 nm, and the hydrogenation is carried out at a liquid feed rate of 1-4 h-1.
EFFECT: producing target products with high selectivity at high process efficiency and feedstock conversion.
25 cl, 8 dwg, 6 tbl, 6 ex
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Authors
Dates
2017-08-02—Published
2015-12-29—Filed