METHOD FOR PRODUCING HIGH-OCTANE PETROL COMPONENT Russian patent published in 2017 - IPC C10G59/02 C10G69/08 

Abstract RU 2640043 C1

FIELD: chemistry.

SUBSTANCE: method includes catalytic reforming of the fraction of 85-180°C, isolating the low-octane benzene-containing fraction from the reformate, hydroisomerizing the isolated fraction or its mixture with a straight-run hydrotreated fraction of 70-85°C and mixing the product with the rest of the reformate. Herewith a fraction containing mainly n-hexane, benzene and heptane is allocated within the temperature range of the starting boiling point of 65-70°C and the end boiling point of 100-105°C, hydroisomerization is carried out at a temperature of 150-350°C, at a pressure of 1.0-5.0 MPa, a volumetric feed rate of the raw material of 0.5-5.0 h -1 and a mole ratio of hydrogen/feedstock of 0.5-5.0 in the presence of a catalyst with subsequent separation from the product of low octane fraction, containing mainly n-heptane and methylhexane, and its recycle in a gas-raw mixture, and produced hydroisomerizate is blended with the remaining portion of the reformate with producing the target product, wherein the hydroisomerization catalyst contains, wt %: platinum and/or palladium 0.1-1.0, zeolite H-MOR or H-β - 5-50 or oxides WO3 and ZrO2 in the amount of 5-25 and 50-80, respectively, and aluminium oxide - the rest. The proposed method allows to produce a reformate with an octane number of 99-105 (IM) at an aromatic hydrocarbon content of 47-54 vol. %, benzene - 0.15-0.20 vol. %.

EFFECT: improving the characteristics of petrol.

3 tbl, 22 ex

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RU 2 640 043 C1

Authors

Belyj Aleksandr Sergeevich

Smolikov Mikhail Dmitrievich

Kiryanov Dmitrij Ivanovich

Shkurenok Violetta Andreevna

Belopukhov Evgenij Aleksandrovich

Yablokova Svetlana Stanislavovna

Kondrashev Dmitrij Olegovich

Klejmenov Andrej Vladimirovich

Egizaryan Arkadij Mamikonovich

Dates

2017-12-26Published

2016-11-24Filed