FIELD: chemistry.
SUBSTANCE: invention relates to the method of producing pentafluoroiodoethane from perfluoro-propene, which includes the interaction of CF3CF=CF2 with the iodine source, such as iodine-halide I-I, I-Br, I-Cl in the presence of inorganic fluoride, or perfluoro-isopropyl-iodide, and sodium methylate in the polar aprotic solvent with the formation of 1,1,1,2,3,3-hexafluoro-2-iodine-3-methoxy-propane, its subsequent demethylation by boiling with pentachloride antimony with obtaining 2,3,3,3-tetrafluoro-2-iodopropionyl fluoride, and decarbonylation of the latter under the action of pentafluoride antimony on heating, which gives pentafluoroiodetane.
EFFECT: use of available non-explosive raw materials.
4 cl, 5 ex
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1,1,1,2,3,3-HEXAFLUORO-2-IODINE-3-METHOXYPROPANE AS SEMI-PRODUCTS FOR PRODUCTION OF FLUORIDE 2,3,3,3-TETRAFLUORO-2-IODPROPIONYL AND METHOD OF PRODUCING LATTER | 2017 |
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Authors
Dates
2018-01-26—Published
2017-05-31—Filed